Innovative solid desiccant dehumidification using distributed microwaves.

Dehumidification is one of the key challenges facing the air conditioning (AC) industry in the treatment of moist air. Over many decades, the dual role of heat exchangers of AC chillers for the sensible and latent cooling of space has hindered the thermal-lift reduction in the refrigeration cycle due to the requirements of water vapor removal at dew-point and heat rejection to the ambient air. These practical constraints of AC chillers have resulted in the leveling of energy efficiency of mechanical vapor compressors (MVC) for many decades. One promising approach to energy efficiency improvement is the decoupling of dehumidification from sensible processes so that innovative but separate processes can be applied. In this paper, an advanced microwave dehumidification method is investigated in the laboratory, where the microwave (2.45 GHz) energy can be irradiated onto the dipole structure of water vapor molecules, desorbing rapidly from the pores of adsorbent. Results show a significant improvement in performance for microwave dehumidification, up to fourfold, as compared to data available in the literature.

Small RNAs and Karma methylation in Elaeis guineensis mother palms are linked to high clonal mantling.

The mantled phenotype is an abnormal somaclonal variant arising from the oil palm cloning process and severe phenotypes lead to oil yield losses. Hypomethylation of the Karma retrotransposon within the B-type MADS-box EgDEF1 gene has been associated with this phenotype. While abnormal Karma-EgDEF1 hypomethylation was detected in mantled clones, we examined the methylation state of Karma in ortets that gave rise to high mantling rates in their clones. Small RNAs (sRNAs) were proposed to play a role in Karma hypomethylation as part of the RNA-directed DNA methylation process, hence differential expression analysis of sRNAs between the ortet groups was conducted. While no sRNA was differentially expressed at the Karma-EgDEF1 region, three sRNA clusters were differentially regulated in high-mantling ortets. The first two down-regulated clusters were possibly derived from long non-coding RNAs while the third up-regulated cluster was derived from the intron of a DnaJ chaperone gene. Several predicted mRNA targets for the first two sRNA clusters conversely displayed increased expression in high-mantling relative to low-mantling ortets. These predicted mRNA targets may be associated with defense or pathogenesis response. In addition, several differentially methylated regions (DMRs) were identified in Karma and its surrounding regions, mainly comprising subtle CHH hypomethylation in high-mantling ortets. Four of the 12 DMRs were located in a region corresponding to hypomethylated areas at the 3'end of Karma previously reported in mantled clones. Further investigations on these sRNAs and DMRs may indicate the predisposition of certain ortets towards mantled somaclonal variation.

A novel zero-liquid discharge desalination system based on the humidification-dehumidification process: A preliminary study.

As a byproduct of desalination plants, brine is increasingly becoming a threat to the environment, and the design of zero-liquid discharge (ZLD) systems is gaining increasing attention. Existing ZLD systems are limited by a high energy intensity and high plant costs of their crystallizers. This study proposes a novel crystallization method based on the humidification-dehumidification (HDH) process, which exhibits the advantages of a low energy consumption, low component costs and a reduced scaling and fouling potential. A simple experimental setup is first designed to demonstrate the feasibility of the proposed system. Brine concentration and salt crystallization are successfully achieved with air heated to 40 °C as the heat source. Afterwards, a thermo-economic analysis is conducted for the whole system. The specific thermal energy and electricity consumption levels are found to range from 700-900 and 5-11 kJ, respectively, per kg of feed brine. The energy consumption is 56% lower than that of a conventional evaporative crystallizer, and the initial plant cost is reduced by 58%.

"Crisis management in the hospitality sector SMEs in Pakistan during COVID-19″.

The COVID-19 pandemic has delivered one of the worst economic shocks in modern history and the hospitality sector has been severely affected. Since small businesses from the hospitality sector are known to be relatively more susceptible to the economic complications arising from a crisis, we explore the underlying factors and management practices that influence their continuity of operations as they continue to struggle with the on-going COVID-19 crisis in Pakistan. Using a phenomenological approach, in-depth interviews were conducted to comprehend the experiences of owners-managers. The findings show that government support, cordial relationships with stakeholders, self-determination of entrepreneurs and formal planning are the most crucial factors that shaped the immediate adjustments of operational activities in response to COVID-19. These resilient practices are hygiene concerns, increased promotion through social media, innovative marketing practices (e.g., revised offerings), operational cost-cutting and employee training to comply with changing standard operating procedures from the government and industry. The practical and theoretical implications are also discussed.

A Universal Mathematical Methodology in Characterization of Materials for Tailored Design of Porous Surfaces.

Understanding adsorption phenomena is essential to optimize and customize the energy transformation in numerous industrial and environmental processes. The complex and heterogeneous structure of the adsorbent surface and the distinct interaction of adsorbent-adsorbate pairs are attributed to the diverse response of adsorption phenomena, measured by the state diagrams of adsorption uptake known as adsorption isotherms. To understand various forms of adsorption isotherms, the surface characteristics of the adsorbent surface with the heterogeneity of adsorption energy sites must be analyzed so that they can be modified for the tailored response of the material. Conventionally, such material synthesis is based on chemical recipes or post-treatment. However, if the adsorbent's surface characteristics and heterogeneity are known, then a directed change in the material structure can be planned for the desired results in the adsorption processes. In this paper, a theoretical and mathematical methodology is discussed to analyze the structure of various adsorbents in terms of the distribution of their adsorption energy sites. The change in their surface is then analyzed, which results in the tailored or customized response of the material.

A Universal Theoretical Framework in Material Characterization for Tailored Porous Surface Design.

The distinct interaction of adsorbate-adsorbent pair is attributed to the characteristics of heterogeneous surface and structure of porous materials. In material science, the porous structure is modified in response to certain applications. Backed by the chemical recipes, such conventional approach rely on the material characterization techniques to verify the resultant porous structure and its interaction with the adsorbate molecules. Such a practice is best assisted by a theoretical approach that can pre-define the required heterogeneous structure of porous surfaces and its role in selective adsorbate-adsorbent interaction, to facilitate material scientists for the synthesis of only those energy sites which can enhance or tailor its responses for a certain application or target. It has been reported here that the understanding of porous structure in terms of energy sites and their distribution, which controls the adsorbate-adsorbent interaction, is the key for porous surface engineering. Understanding of such porous surface characteristics empower the scientists to alter kinetics and thermodynamics of material according to the 'sweet spots' of an application. Therefore, a theoretical framework, to express the energy sites and their distribution over the porous heterogeneous surface, is demonstrated here as a prerequisite criterion for porous material development and characterization.

Desalination Processes' Efficiency and Future Roadmap.

For future sustainable seawater desalination, the importance of achieving better energy efficiency of the existing 19,500 commercial-scale desalination plants cannot be over emphasized. The major concern of the desalination industry is the inadequate approach to energy efficiency evaluation of diverse seawater desalination processes by omitting the grade of energy supplied. These conventional approaches would suffice if the efficacy comparison were to be conducted for the same energy input processes. The misconception of considering all derived energies as equivalent in the desalination industry has severe economic and environmental consequences. In the realms of the energy and desalination system planners, serious judgmental errors in the process selection of green installations are made unconsciously as the efficacy data are either flawed or inaccurate. Inferior efficacy technologies' implementation decisions were observed in many water-stressed countries that can burden a country's economy immediately with higher unit energy cost as well as cause more undesirable environmental effects on the surroundings. In this article, a standard primary energy-based thermodynamic framework is presented that addresses energy efficacy fairly and accurately. It shows clearly that a thermally driven process consumes 2.5-3% of standard primary energy (SPE) when combined with power plants. A standard universal performance ratio-based evaluation method has been proposed that showed all desalination processes performance varies from 10-14% of the thermodynamic limit. To achieve 2030 sustainability goals, innovative processes are required to meet 25-30% of the thermodynamic limit.

IoT Elements, Layered Architectures and Security Issues: A Comprehensive Survey.

The use of the Internet is growing in this day and age, so another area has developed to use the Internet, called Internet of Things (IoT). It facilitates the machines and objects to communicate, compute and coordinate with each other. It is an enabler for the intelligence affixed to several essential features of the modern world, such as homes, hospitals, buildings, transports and cities. The security and privacy are some of the critical issues related to the wide application of IoT. Therefore, these issues prevent the wide adoption of the IoT. In this paper, we are presenting an overview about different layered architectures of IoT and attacks regarding security from the perspective of layers. In addition, a review of mechanisms that provide solutions to these issues is presented with their limitations. Furthermore, we have suggested a new secure layered architecture of IoT to overcome these issues.

A Universal Isotherm Model to Capture Adsorption Uptake and Energy Distribution of Porous Heterogeneous Surface.

The adsorbate-adsorbent thermodynamics are complex as it is influenced by the pore size distributions, surface heterogeneity and site energy distribution, as well as the adsorbate properties. Together, these parameters defined the adsorbate uptake forming the state diagrams, known as the adsorption isotherms, when the sorption site energy on the pore surfaces are favorable. The available adsorption models for describing the vapor uptake or isotherms, hitherto, are individually defined to correlate to a certain type of isotherm patterns. There is yet a universal approach in developing these isotherm models. In this paper, we demonstrate that the characteristics of all sorption isotherm types can be succinctly unified by a revised Langmuir model when merged with the concepts of Homotattic Patch Approximation (HPA) and the availability of multiple sets of site energy accompanied by their respective fractional probability factors. The total uptake (q/q*) at assorted pressure ratios (P/P s ) are inextricably traced to the manner the site energies are spread, either naturally or engineered by scientists, over and across the heterogeneous surfaces. An insight to the porous heterogeneous surface characteristics, in terms of adsorption site availability has been presented, describing the unique behavior of each isotherm type.

A reappraisal of contributing factors leading to shunt infection.

BACKGROUND: Central nervous shunt infection (CNSI) is a cause of significant morbidity, causing shunt malfunction and chronic ill health. It can also lead to prolong hospital stay. The aim of this study was to look into the factors responsible for neurosurgical shunt infection and measures to prevent them. METHOD: This retrospective case study was done with nonrandomized convenience sampling. We studied 121 patients who underwent neurosurgical shunt operations during year 1994 to 1999. These patients received pre, per and post operative antibiotics to combat shunt infection. Study design was retrospective case study with non randomized convenience sampling. RESULT: Out of 121 patients, 65 patients were females and 56 males. The total number of shunts procedures performed in these patients was 151. Ninety-seven patients operated once for shunt procedure. Eighty-three (83) patients underwent ventriculo-peritoneal shunt, 10 patients underwent lumbo-peritoneal shunt, 3 had ventriculo-pleural shunt and 1 had ventriculo-atrial shunting done. Three patients developed shunt infection, only one had true primary infection. All were adults with male to female ratio of 2 to 1 and in all of them shunt was inserted first time. CONCLUSION: Strict aseptic technique and prophylactic use of antibiotics have critical role in the prevention of shunt infections.